MATERIAL SAFETY DATA SHEET

M.S.D.S.

While NACCO Products believes that data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data herein is not to be taken as a warranty or representation for which NACCO Products assumes legal responsibility. They are offered solely for your consideration, investigation and verification. Any use of this data and information must be determined by the user with applicable Federal and State laws and regulations.

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I: PRODUCT IDENTIFICATION INFORMATION

TRADENAME (as labeled): ULTRAFINE FILM DEVELOPER

Chemical Name:

Chemical Family: Powder Formula

Formula: Proprietary - Photographic

Synonyms:

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EMERGENCY CONTACT:

CHEMTREC

1-800-424-9300

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MANUFACTURER'S NAME: NACCO/ NATIONAL RESEARCH & CHEMICAL

444 EAST GARDENA BLVD.

GARDENA, CA. 90248

PHONE: (310) 352-6999

FAX: (310) 527-9963

Department of Transportation: (Shipping Information)

Date Prepared: October 2002

Hazardous Classification: None regulated

Shipping Name: Chemicals N.O.S Dot Class: 55

Packing Group: UN/NA Number:

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II: PHYSICAL PROPERTIES

V.O.C.: N/A Appearance: White powder

Vapor Density (air = 1): N/A Vapor Pressure (at 20°C): Not applicable Specific Gravity(H2O=1): N/A Boiling Point/Range°F: Not Applicable

Solubility in Water: Complete Evaporation Rate: N/A

Odor: Faint odor pH (of 1% solution): 9.6 to 9.8

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III: COMPOSITION INFORMATION

COMPONENTS CAS#

Sodium Sulfite 7757-83-7

Hyroquinone 123-31-9

1-Phenyl-3-Pyrazolidinone 92-43-3

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IV: POTENTIAL HEALTH HAZARD DATA

EFFECTS OF ACUTE OVER- EXPOSURE:

Eye Contact: Can and will cause irritation.

Skin Absorption: May cause irritation. Avoid prolonged or repeated contact.

Inhalation: Avoid breathing dust. Dust may cause upper respiratory tract irritation.

Skin Contact: May cause irritation.

Swallowing: Maybe harmful , May cause nausea, dizziness and headache.

Other Health Hazards: None known.

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V: FIRST AID EMERGENCY PROCEDURES

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. If irritation occurs, get medical attention.

Skin Contact: Flush with plenty of soap and water. If irritation continues get medical attention.

Inhalation: Immediately move to fresh air.

Swallowed: If conscious, give 2 large glasses of water. Immediately contact physician. IF UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH.

Other: None known.

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VI: FIRE AND EXPLOSION HAZARD DATA

Flash Point: Not-Flammable

Flammable Limits: N/A

Lower: Upper:

Extinguishing Media: Material is not flammable

Water Spray: X Foam: X

Carbon Dioxide: X Dry Chemical: X

Use extinguishing media appropriate for material for surrounding fire.

Special Fire Fighting Procedures: Wear Self-contained NIOSH Approved breathing apparatus.

Unusual Fire/Explosion Hazard: None Known

Other: None __________________________________________________________________________________

VII: REACTIVITY DATA

Stability:

Stable: X Unstable:

Conditions to Avoid: Strong acids will generate heat and sulfur dioxide.

Incompatibility: Strong oxidizer: cause vigorous exothermic reactions.

ACIDS: Releases sulfur dioxide gas.

Hazardous combustion’s

Or Decomposition Products: Sulfur Dioxide and Sodium Sulfide residue.

Hazardous Polymerization:

May Occur: Will Not Occur: X

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VIII: SPILL, LEAK AND DISPOSAL PROCEDURES

Steps to be taken: Contain spill by inorganic, non- combustible absorbent, such as; sand, pads or inert material. Shovel into empty container and cover. Rinse any residue with plenty of water. Provide Ventilation.

Preparing waste for disposal: For disposal or discharge, contact Federal, State or Local Agencies.

NOTE: DISPOSE OF ALL WASTE ACCORDING WITH FEDERAL, STATE AND LOCAL REGULATIONS.

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IX: SPECIAL HANDLING INFORMATION

Respiratory Protection: Use approved dust respirators

Ventilation: Local exhaust is recommended. Use in well ventilated area.

Protective Gloves: Rubber or plastic, gloves.

Eye Protection: Safety glasses or goggles should be worn in chemical handling.

Other clothing and Equipment: Apron or lab coat. Also safety shower and eye bath.

Work practices, hygienic requirements: Avoid unnecessary personal contact. Wash hands thoroughly with soap and water after handling.

Other handling and storage requirements: Store above 48°F. Keep tightly sealed.

KEEP OUT OF REACH OF CHILDREN.

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X: OTHER INFORMATION

HMIS RATINGS CHART:

HMIS:

Health: 1 Flammability: 0

Reactivity: 0 Personal Protection: B

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SARA TITLE III - SECTION 311/312:

N- Fire Hazard

N-Sudden release of pressure hazard

N-Reactivity hazard

N-Immediate health hazard (acute)

N-Delayed health hazard (chronic)

SARA TITLE III - SECTION 302/304:

This product does not contain extremely hazardous substances at levels, which could require reporting.

SARA TITLE III = SECTION 313:

This product does not contain toxic chemicals at levels, which require reporting.

OZONE - DEPLETING CHEMICALS:

None

CERCLA REPORTABLE QUANTITY:

None

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TSCA STATUS:

All components of these products are on the TSCA Inventory or are exempt from TSCA Inventory requirements.

OSHA REGULATIONS:

Do not apply to this material or it’s components. At levels which require reporting.

CALIFORNIA PROPOSITION 65:

This product does not contain chemicals known to the State of California to cause cancer.

CALIFORNIA SCAQMO RULE 443.1:

VOC - not applicable.